Facile formation of five-membered N-heterocyclic zirconacycloallenoids.

نویسندگان

  • Santhosh Kumar Podiyanachari
  • Roland Fröhlich
  • Constantin G Daniliuc
  • Jeffrey L Petersen
  • Gerald Kehr
  • Gerhard Erker
  • Noriyuki Suzuki
  • Shin Yuasa
  • Keita Hagimori
  • Shota Inoue
  • Takumi Asada
  • Takahiko Takemoto
  • Yoshiro Masuyama
چکیده

The reaction of η(2)-iminozirconocene chloride complexes with trimethylsilylethynyl lithium leads to rapid C-C coupling at room temperature to yield the corresponding five-membered aza-zirconacycloallenoids. Such compounds were also obtained by trapping of in situ generated zirconocene with alkynyl imines.

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عنوان ژورنال:
  • Dalton transactions

دوره 41 35  شماره 

صفحات  -

تاریخ انتشار 2012